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FJX_spec.dat
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UCI FJX v6.8c JPL10+2013 fixes: Q1d, Acetone! others, derived fort10-2013b.x
NW-JValues 71 18 NQQQ,NWWW - nominally NJVAL = NQQQ (# Xsects)
w-eff (nm) 187. 191. 193. 196. 202. 208.
211. 214. 261. 267. 277. 295.
303. 310. 316. 333. 380. 574.
SOL#/cm2/s 1.391E+12 1.627E+12 1.664E+12 9.278E+11 7.842E+12 4.680E+12 SUSIM average
9.918E+12 1.219E+13 6.364E+14 4.049E+14 3.150E+14 5.889E+14 11Nov94 low
7.678E+14 5.045E+14 8.902E+14 3.853E+15 1.547E+16 2.131E+17 29Mar92 high
Raylay cm2 5.073E-25 4.479E-25 4.196E-25 3.906E-25 3.355E-25 2.929E-25
2.736E-25 2.581E-25 1.049E-25 9.492E-26 8.103E-26 6.131E-26
5.422E-26 4.923E-26 4.514E-26 3.643E-26 2.087E-26 3.848E-27
O2 180 1.727E-21 1.989E-22 3.004E-23 9.833E-24 7.306E-24 6.827E-24 J10X
6.238E-24 5.748E-24 1.153E-25 5.030E-25 4.150E-25 0.000E+00 corr.bin8
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
O2 260 2.273E-21 3.070E-22 4.943E-23 1.408E-23 7.688E-24 6.827E-24 J10X
6.238E-24 5.888E-24 1.153E-25 5.030E-25 4.150E-25 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
O2 300 2.763E-21 4.269E-22 7.478E-23 2.100E-23 8.350E-24 6.827E-24 J10X
6.238E-24 5.994E-24 1.153E-25 5.030E-25 4.150E-25 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
O3 218 5.988E-19 4.859E-19 4.307E-19 3.654E-19 3.410E-19 4.849E-19 J10x
6.534E-19 9.320E-19 8.757E-18 3.513E-18 1.508E-18 7.925E-19 +IUPAC
2.456E-19 8.904E-20 3.661E-20 4.539E-21 6.167E-23 1.666E-21 2/2013
O3 258 5.989E-19 4.862E-19 4.314E-19 3.666E-19 3.421E-19 4.845E-19 J10x
6.519E-19 9.299E-19 8.826E-18 3.566E-18 1.547E-18 8.260E-19
2.617E-19 9.739E-20 4.139E-20 5.515E-21 6.167E-23 1.666E-21
O3 298 5.990E-19 4.866E-19 4.320E-19 3.678E-19 3.432E-19 4.840E-19 J10x
6.504E-19 9.278E-19 8.896E-18 3.618E-18 1.586E-18 8.595E-19
2.778E-19 1.058E-19 4.617E-20 6.493E-21 6.167E-23 1.666E-21
O3(1D) 200 4.842E-01 4.922E-01 5.071E-01 5.228E-01 6.040E-01 6.803E-01 J10x
7.190E-01 7.549E-01 9.000E-01 8.989E-01 8.929E-01 9.000E-01 3/2013
8.901E-01 4.130E-01 8.985E-02 6.782E-02 0.000E+00 0.000E+00
O3(1D) 260 4.843E-01 4.922E-01 5.072E-01 5.229E-01 6.040E-01 6.802E-01 J10x
7.189E-01 7.549E-01 9.000E-01 8.989E-01 8.929E-01 9.000E-01
8.916E-01 4.656E-01 1.417E-01 6.995E-02 0.000E+00 0.000E+00
O3(1D) 320 4.843E-01 4.922E-01 5.072E-01 5.229E-01 6.040E-01 6.805E-01 J10x
7.189E-01 7.550E-01 9.000E-01 8.989E-01 8.929E-01 9.000E-01
8.967E-01 5.852E-01 2.919E-01 7.943E-02 0.000E+00 0.000E+00
NO x298 6.054E-19 6.936E-19 3.475E-19 0.000E+00 0.000E+00 0.000E+00 J10x0.6
0.000E+00 8.892E-21 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
H2SO4 x298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Mills
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2.542E-25
H2COa 223 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.143E-21 1.021E-20 1.269E-20 2.323E-20
2.498E-20 1.133E-20 2.183E-20 4.746E-21 0.000E+00 0.000E+00
H2COa 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.147E-21 1.018E-20 1.266E-20 2.315E-20
2.497E-20 1.131E-20 2.189E-20 4.751E-21 0.000E+00 0.000E+00
H2COb 223 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.642E-21 5.787E-21 5.316E-21 8.181E-21
7.917E-21 4.011E-21 1.081E-20 1.082E-20 2.088E-22 0.000E+00
H2COb 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.649E-21 5.768E-21 5.305E-21 8.154E-21
7.914E-21 4.002E-21 1.085E-20 1.085E-20 2.081E-22 0.000E+00
H2O2 200 2.325E-19 4.629E-19 5.394E-19 5.429E-19 4.447E-19 3.755E-19 J10
3.457E-19 3.197E-19 5.346E-20 4.855E-20 3.423E-20 8.407E-21
5.029E-21 3.308E-21 2.221E-21 8.598E-22 1.807E-23 0.000E+00
H2O2 300 2.325E-19 4.629E-19 5.394E-19 5.429E-19 4.447E-19 3.755E-19 J10
3.457E-19 3.197E-19 5.465E-20 4.966E-20 3.524E-20 9.354E-21
5.763E-21 3.911E-21 2.718E-21 1.138E-21 2.419E-23 0.000E+00
CH3OOH 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 3.120E-19 J10
2.882E-19 2.250E-19 2.716E-20 2.740E-20 2.143E-20 5.624E-21
3.520E-21 2.403E-21 1.697E-21 7.230E-22 6.973E-23 0.000E+00
NO2 200 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.835E-20 4.693E-20 7.705E-20 1.078E-19
1.470E-19 1.832E-19 2.181E-19 3.138E-19 4.321E-19 1.386E-22
NO2 294 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.313E-20 4.694E-20 7.553E-20 1.063E-19
1.477E-19 1.869E-19 2.295E-19 3.448E-19 4.643E-19 4.345E-22
NO3 190 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10X
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 NO3b=>NO+O2
0.000E+00 0.000E+00 0.000E+00 0.000E+00 5.294E-21 1.112E-18 NO3a=>NO2+O
NO3 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10X
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 use Jb/Jtot
0.000E+00 0.000E+00 0.000E+00 0.000E+00 3.796E-21 8.713E-19 =0.118
N2O5 233 0.000E+00 0.000E+00 8.922E-19 1.183E-18 5.868E-18 4.682E-18 J10
3.395E-18 2.613E-18 2.138E-19 2.155E-19 1.988E-19 3.772E-20
2.182E-20 1.334E-20 8.419E-21 2.621E-21 1.313E-22 1.159E-25
N2O5 300 0.000E+00 0.000E+00 1.078E-18 1.429E-18 7.088E-18 5.655E-18 J10
4.101E-18 3.156E-18 2.606E-19 2.645E-19 2.454E-19 5.154E-20
3.210E-20 2.135E-20 1.468E-20 5.902E-21 6.002E-22 1.290E-24
HNO2 300 9.693E-19 1.387E-18 1.574E-18 1.808E-18 2.154E-18 2.188E-18 J10
2.079E-18 1.911E-18 1.171E-19 1.849E-19 1.489E-19 5.487E-21
9.353E-21 1.895E-20 3.195E-20 9.008E-20 6.900E-20 0.000E+00
HNO3 200 4.169E-18 8.113E-18 8.882E-18 8.211E-18 3.777E-18 1.288E-18 J10
6.882E-19 4.998E-19 1.611E-20 1.794E-20 1.848E-20 3.383E-21
1.374E-21 5.442E-22 2.087E-22 2.118E-23 8.193E-26 0.000E+00
HNO3 300 4.284E-18 8.419E-18 9.368E-18 9.112E-18 4.462E-18 1.551E-18 J10
8.426E-19 5.852E-19 1.855E-20 2.162E-20 2.299E-20 4.371E-21
1.920E-21 8.312E-22 3.573E-22 4.706E-23 2.539E-25 0.000E+00
HNO4 300 4.631E-18 7.576E-18 8.407E-18 7.479E-18 4.744E-18 2.854E-18 J10
2.217E-18 1.843E-18 2.799E-19 2.210E-19 1.539E-19 2.685E-20
1.171E-20 5.683E-21 3.102E-21 8.269E-22 1.309E-23 4.694E-23
ClNO3ax200 3.222E-19 7.351E-19 9.688E-19 1.664E-18 1.614E-18 1.774E-18 J10
1.921E-18 2.009E-18 1.948E-19 2.801E-19 2.046E-19 2.043E-20
1.088E-20 6.655E-21 4.564E-21 2.324E-21 9.207E-22 6.955E-24
ClNO3ax300 3.527E-19 8.041E-19 1.055E-18 1.815E-18 1.705E-18 1.805E-18 J10
1.928E-18 2.001E-18 2.319E-19 3.033E-19 2.140E-19 2.787E-20
1.564E-20 1.002E-20 7.086E-21 3.404E-21 1.177E-21 9.858E-24
ClNO3bx200 2.147E-19 4.899E-19 6.457E-19 1.109E-18 1.076E-18 1.183E-18 J10
1.281E-18 1.339E-18 1.299E-19 1.867E-19 1.364E-19 1.362E-20
7.256E-21 4.187E-21 2.372E-21 7.063E-22 2.641E-23 0.000E+00
ClNO3bx300 2.351E-19 5.361E-19 7.034E-19 1.210E-18 1.136E-18 1.203E-18 J10
1.285E-18 1.334E-18 1.546E-19 2.022E-19 1.427E-19 1.858E-20
1.043E-20 6.303E-21 3.680E-21 1.052E-21 3.330E-23 0.000E+00
ClNO2 x298 1.049E-17 1.019E-17 9.285E-18 8.613E-18 4.225E-18 3.170E-18 J10
3.251E-18 3.440E-18 5.935E-19 5.967E-19 4.396E-19 1.529E-19
1.346E-19 1.204E-19 1.035E-19 6.193E-20 1.026E-20 3.270E-21
Br2 298 5.620E-21 5.620E-21 5.645E-21 5.620E-21 6.527E-21 8.167E-21 J10
8.953E-21 9.579E-21 3.185E-21 2.293E-21 1.207E-21 2.027E-22
1.134E-22 1.497E-22 3.956E-22 6.865E-21 3.594E-19 1.157E-19
BrNO2 298 3.006E-17 3.905E-17 4.383E-17 5.035E-17 4.817E-17 3.238E-17 J10
2.220E-17 1.446E-17 2.260E-18 1.318E-18 1.072E-18 3.169E-19
1.701E-19 1.149E-19 1.063E-19 1.369E-19 1.577E-19 1.374E-20
Cl2 x200 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 5.482E-21 2.419E-20 4.980E-20 8.413E-20
1.393E-19 1.878E-19 2.265E-19 2.524E-19 6.328E-20 6.963E-22
Cl2 x300 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 6.002E-21 2.708E-20 5.409E-20 8.855E-20
1.404E-19 1.844E-19 2.185E-19 2.411E-19 6.552E-20 6.823E-22
HOCl x300 0.000E+00 3.695E-21 1.571E-20 2.435E-20 5.887E-20 5.424E-20 J10
5.798E-20 6.694E-20 1.019E-19 6.541E-20 5.430E-20 5.570E-20
6.067E-20 5.955E-20 5.376E-20 3.120E-20 6.529E-21 1.273E-23
OClO x204 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 4.061E-19 5.616E-19 8.776E-19 1.211E-18
1.857E-18 2.606E-18 2.522E-18 4.227E-18 3.254E-18 4.061E-20
ClOO x298 6.110E-18 6.110E-18 6.110E-18 6.110E-18 6.110E-18 6.110E-18 J10
6.110E-18 6.110E-18 1.306E-17 3.649E-18 2.365E-18 2.000E-18
2.000E-18 2.000E-18 2.000E-18 2.000E-18 2.000E-18 2.000E-18
Cl2O2 x220 0.000E+00 2.177E-19 9.321E-19 1.435E-18 3.578E-18 3.009E-18 J10
2.648E-18 2.357E-18 4.063E-18 1.971E-18 1.236E-18 8.681E-19
5.719E-19 4.163E-19 3.234E-19 1.921E-19 3.857E-20 6.131E-22
ClO x300 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 4.737E-18 3.262E-18 1.858E-18 1.428E-18
5.982E-19 3.548E-19 1.427E-19 0.000E+00 0.000E+00 0.000E+00
BrO 300 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 0.000E+00 5.620E-19 1.202E-18 2.008E-18
3.239E-18 4.520E-18 5.064E-18 5.809E-18 7.350E-19 0.000E+00
BrNO3 200 0.000E+00 0.000E+00 5.484E-19 7.245E-19 3.702E-18 3.475E-18 J10
3.182E-18 2.978E-18 5.304E-19 6.086E-19 4.489E-19 1.963E-19
1.584E-19 1.307E-19 1.110E-19 8.033E-20 3.377E-20 1.270E-21
BrNO3 300 0.000E+00 0.000E+00 8.026E-19 1.071E-18 5.166E-18 4.190E-18 J10
3.467E-18 3.039E-18 5.567E-19 5.989E-19 4.528E-19 2.098E-19
1.705E-19 1.425E-19 1.207E-19 8.648E-20 3.716E-20 1.445E-21
HOBr 300 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.324E-19 2.011E-19 2.202E-19 2.196E-19
1.726E-19 1.367E-19 1.157E-19 1.125E-19 6.197E-20 2.755E-21
BrCl x200 0.000E+00 0.000E+00 3.138E-21 3.852E-21 2.798E-20 4.258E-20 J10
4.915E-20 5.482E-20 2.293E-20 1.531E-20 7.620E-21 1.983E-21
4.115E-21 9.571E-21 2.126E-20 1.102E-19 3.272E-19 1.980E-20
BrCl x300 0.000E+00 0.000E+00 3.356E-21 4.152E-21 2.906E-20 4.234E-20 J10
4.785E-20 5.244E-20 2.430E-20 1.596E-20 8.718E-21 3.854E-21
7.582E-21 1.550E-20 3.038E-20 1.223E-19 3.184E-19 2.045E-20
N2O x200 1.076E-19 8.490E-20 6.974E-20 5.200E-20 2.171E-20 6.405E-21 J10
3.097E-21 2.473E-21 3.308E-25 1.048E-23 4.114E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
N2O x300 1.225E-19 1.006E-19 8.493E-20 6.658E-20 3.135E-20 1.150E-20 J10
6.282E-21 4.614E-21 1.501E-24 4.070E-23 1.173E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CFCl3 x220 2.177E-18 1.608E-18 1.302E-18 9.616E-19 4.538E-19 1.638E-19 J10
9.562E-20 7.113E-20 4.112E-23 7.026E-22 1.892E-21 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CFCl3 x298 2.237E-18 1.652E-18 1.339E-18 9.882E-19 4.884E-19 2.026E-19 J10
1.266E-19 9.361E-20 9.732E-23 1.289E-21 2.955E-21 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CF2Cl2x220 7.001E-19 4.044E-19 2.780E-19 1.507E-19 4.142E-20 6.627E-21 J10
2.876E-21 5.395E-21 2.698E-25 8.767E-24 3.338E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CF2Cl2x300 1.012E-18 5.844E-19 4.020E-19 2.178E-19 6.291E-20 1.258E-20 J10
5.959E-21 8.779E-21 8.279E-25 2.466E-23 8.261E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F113 x210 1.061E-18 6.852E-19 4.983E-19 2.810E-19 8.627E-20 2.020E-20 J10
1.043E-20 1.272E-20 4.158E-24 6.808E-23 1.800E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F113 x300 9.495E-19 5.932E-19 4.317E-19 2.618E-19 9.300E-20 2.661E-20 J10
1.453E-20 1.395E-20 6.689E-24 1.046E-22 2.685E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F114 x210 1.291E-19 5.656E-20 3.403E-20 1.585E-20 4.491E-21 9.317E-22 J10
4.480E-22 6.972E-22 9.733E-26 2.472E-24 6.812E-24 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F114 x300 1.203E-19 5.566E-20 3.520E-20 1.825E-20 6.078E-21 1.642E-21 J10
8.743E-22 9.578E-22 2.385E-25 6.055E-24 1.608E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F115 x300 6.876E-21 2.986E-21 1.891E-21 1.018E-21 3.531E-22 1.124E-22 J10
6.079E-23 6.176E-23 5.728E-27 6.317E-25 1.345E-24 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CCl4 x200 3.610E-18 1.670E-18 1.100E-18 7.155E-19 6.122E-19 4.744E-19 J10
3.774E-19 2.864E-19 6.486E-22 7.133E-21 1.323E-20 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CCl4 x300 3.707E-18 1.712E-18 1.124E-18 7.237E-19 6.267E-19 5.208E-19 J10
4.392E-19 3.544E-19 1.614E-21 1.234E-20 1.854E-20 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH3Cl x200 2.838E-19 1.310E-19 8.192E-20 3.940E-20 1.098E-20 2.102E-21 J10
9.710E-22 1.654E-21 1.353E-25 4.702E-24 1.424E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH3Cl x300 2.842E-19 1.308E-19 8.238E-20 4.125E-20 1.284E-20 3.135E-21 J10
1.619E-21 2.046E-21 2.691E-25 9.348E-24 2.828E-23 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
MeCCl3x200 2.720E-18 2.025E-18 1.688E-18 1.354E-18 7.434E-19 3.348E-19 J10
2.026E-19 1.374E-19 5.478E-23 1.440E-21 4.133E-21 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
MeCCl3x300 2.722E-18 2.020E-18 1.680E-18 1.338E-18 7.420E-19 3.515E-19 J01
2.232E-19 1.574E-19 2.197E-22 2.618E-21 5.521E-21 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH2Cl2x200 1.091E-18 6.168E-19 4.117E-19 2.063E-19 5.999E-20 1.421E-20 J10
7.370E-21 9.789E-21 4.003E-24 5.376E-23 1.269E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH2Cl2x300 9.995E-19 5.790E-19 3.970E-19 2.144E-19 7.138E-20 2.124E-20 J10
1.203E-20 1.237E-20 7.640E-24 1.026E-22 2.385E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CHF2Clx200 7.852E-21 2.816E-21 1.551E-21 6.716E-22 1.891E-22 4.359E-23 J10
2.467E-23 3.483E-23 0.000E+00 2.454E-27 4.684E-25 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CHF2Clx300 7.528E-21 2.775E-21 1.578E-21 7.386E-22 2.375E-22 6.207E-23 J10
3.512E-23 4.089E-23 0.000E+00 3.494E-27 6.670E-25 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F123 x210 9.371E-19 5.088E-19 3.401E-19 1.837E-19 6.049E-20 1.614E-20 J10
8.774E-21 9.599E-21 4.437E-24 6.935E-23 1.699E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F123 x295 1.037E-18 6.011E-19 4.213E-19 2.461E-19 8.860E-20 2.646E-20 J10
1.495E-20 1.438E-20 1.191E-23 1.409E-22 3.152E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F141b x200 1.165E-18 7.326E-19 5.257E-19 3.034E-19 9.839E-20 2.384E-20 J10
1.224E-20 1.398E-20 2.005E-24 6.588E-23 2.015E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F141b x300 1.126E-18 7.466E-19 5.559E-19 3.448E-19 1.221E-19 3.303E-20 J10
1.757E-20 1.737E-20 5.164E-24 1.146E-22 3.133E-22 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F142b x210 2.253E-20 8.483E-21 4.768E-21 2.113E-21 6.068E-22 1.276E-22 J10
6.211E-23 9.375E-23 0.000E+00 1.766E-25 8.252E-25 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
F142b x298 2.842E-20 1.172E-20 6.981E-21 3.370E-21 1.059E-21 2.543E-22 J10
1.303E-22 1.602E-22 0.000E+00 4.755E-25 1.964E-24 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH3Br x200 1.064E-18 4.918E-19 5.748E-19 6.814E-19 7.562E-19 6.868E-19 J10
6.096E-19 5.216E-19 6.038E-21 3.133E-20 3.378E-20 9.878E-26
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH3Br x300 1.091E-18 5.041E-19 5.891E-19 6.986E-19 7.717E-19 6.999E-19 J10
6.239E-19 5.378E-19 7.764E-21 3.424E-20 3.540E-20 7.365E-25
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
H1211 x200 5.810E-19 6.607E-19 7.844E-19 9.493E-19 1.290E-18 1.385E-18 J10
1.313E-18 1.181E-18 2.933E-20 8.981E-20 8.335E-20 2.038E-23
3.698E-24 1.109E-24 3.929E-25 5.010E-27 0.000E+00 0.000E+00
H1211 x300 5.063E-19 5.757E-19 6.828E-19 8.271E-19 1.105E-18 1.166E-18 J10
1.105E-18 9.995E-19 3.541E-20 8.319E-20 7.215E-20 1.068E-22
2.727E-23 8.654E-24 3.067E-24 3.910E-26 0.000E+00 0.000E+00
H1301 x200 6.268E-20 8.611E-20 9.979E-20 1.158E-19 1.400E-19 1.404E-19 J10
1.282E-19 1.096E-19 6.655E-22 5.389E-21 6.890E-21 1.311E-25
1.580E-26 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
H1301 x300 5.426E-20 7.273E-20 8.354E-20 9.598E-20 1.173E-19 1.227E-19 J10
1.165E-19 1.047E-19 1.413E-21 7.024E-21 7.262E-21 4.028E-25
4.856E-26 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
H2402 x200 1.038E-18 1.137E-18 1.167E-18 1.193E-18 1.145E-18 1.013E-18 J10
9.185E-19 8.183E-19 1.999E-20 6.373E-20 5.698E-20 2.284E-24
6.437E-25 2.441E-25 1.156E-25 1.879E-27 0.000E+00 0.000E+00
H2402 x300 1.023E-18 1.133E-18 1.175E-18 1.221E-18 1.213E-18 1.101E-18 J10
1.008E-18 9.029E-19 2.581E-20 7.236E-20 6.360E-20 4.568E-23
1.287E-23 4.881E-24 2.311E-24 3.757E-26 0.000E+00 0.000E+00
CH2Br2 200 2.106E-18 2.100E-18 2.205E-18 2.384E-18 2.343E-18 2.413E-18 J10
2.691E-18 3.182E-18 1.489E-19 4.916E-19 3.187E-19 5.186E-23
8.043E-24 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CH2Br2 300 1.983E-18 1.977E-18 2.076E-18 2.244E-18 2.206E-18 2.272E-18 J10
2.404E-18 2.561E-18 1.724E-19 3.708E-19 2.349E-19 2.670E-22
4.141E-23 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
CHBr3 210 5.928E-18 4.527E-18 4.157E-18 3.943E-18 4.498E-18 4.775E-18 J10
5.072E-18 5.503E-18 7.881E-19 9.160E-19 5.449E-19 7.716E-21
1.996E-21 6.036E-22 2.461E-22 3.240E-23 3.414E-25 0.000E+00
CHBr3 300 5.630E-18 4.299E-18 3.948E-18 3.744E-18 4.272E-18 4.535E-18 J10
4.817E-18 5.227E-18 8.969E-19 9.049E-19 5.338E-19 1.676E-20
5.066E-21 1.783E-21 7.401E-22 9.748E-23 1.027E-24 0.000E+00
CH3I 243 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
3.958E-20 4.769E-20 8.257E-19 2.154E-19 7.349E-20 3.351E-20
1.034E-20 4.435E-21 2.272E-21 4.393E-22 4.052E-24 0.000E+00
CH3I 300 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
3.958E-20 4.769E-20 8.376E-19 2.438E-19 9.355E-20 4.680E-20
1.529E-20 6.532E-21 3.328E-21 6.783E-22 1.038E-23 0.000E+00
CF3I 243 8.229E-21 3.885E-21 2.404E-21 1.653E-21 1.772E-21 2.856E-21 J10
4.178E-21 6.205E-21 5.540E-19 3.605E-19 2.108E-19 1.330E-19
4.992E-20 2.036E-20 9.495E-21 1.567E-21 1.868E-23 0.000E+00
CF3I 300 8.229E-21 3.885E-21 2.404E-21 1.653E-21 1.772E-21 2.856E-21 J10
4.178E-21 6.205E-21 5.164E-19 3.545E-19 2.275E-19 1.544E-19
6.552E-20 2.972E-20 1.471E-20 2.620E-21 3.944E-23 0.000E+00
OCS 200 5.275E-20 3.879E-20 2.920E-20 2.343E-20 6.049E-20 1.232E-19 J10
1.691E-19 2.181E-19 9.974E-21 4.126E-20 2.417E-20 9.292E-25
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
OCS 300 7.547E-20 5.314E-20 3.637E-20 2.436E-20 6.009E-20 1.222E-19 J10
1.689E-19 2.186E-19 1.382E-20 4.616E-20 2.470E-20 3.294E-24
7.435E-26 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
HAC 298 2.430E-20 2.430E-20 2.430E-20 2.430E-20 2.430E-20 2.430E-20 J10
2.430E-20 2.430E-20 5.336E-20 4.061E-20 2.757E-20 1.735E-20
6.953E-21 2.917E-21 1.403E-21 4.377E-22 0.000E+00 0.000E+00
PAN 250 7.378E-19 1.680E-18 2.179E-18 3.774E-18 3.022E-18 2.163E-18 J10
1.735E-18 1.343E-18 6.568E-20 9.393E-20 8.602E-20 2.421E-21
9.352E-22 4.320E-22 2.291E-22 5.393E-23 7.265E-25 0.000E+00
PAN 298 8.121E-19 1.847E-18 2.379E-18 4.129E-18 3.193E-18 2.239E-18 J10
1.803E-18 1.407E-18 7.914E-20 1.055E-19 9.304E-20 3.531E-21
1.414E-21 6.696E-22 3.632E-22 9.109E-23 1.324E-24 0.000E+00
CH3NO3 200 4.459E-18 8.856E-18 1.020E-17 1.021E-17 6.757E-18 3.480E-18 J10
2.248E-18 1.458E-18 2.364E-20 4.404E-20 6.296E-20 3.955E-21
1.626E-21 6.610E-22 2.584E-22 2.194E-23 2.573E-27 0.000E+00
CH3NO3 300 6.234E-18 1.238E-17 1.426E-17 1.427E-17 9.445E-18 4.866E-18 J10
3.143E-18 2.038E-18 3.219E-20 6.182E-20 8.858E-20 6.137E-21
2.740E-21 1.236E-21 5.475E-22 6.702E-23 1.287E-26 0.000E+00
ActAldp177 0.000E+00 0.000E+00 1.989E-23 0.000E+00 3.699E-22 4.938E-22 CH3CO IUPAC 2014
4.737E-22 4.659E-22 2.450E-20 3.409E-20 3.820E-20 3.732E-20 sheet P2 298K
2.707E-20 1.579E-20 6.566E-21 3.883E-22 5.683E-26 0.000E+00 q2=0.88 (CH3+HCO)
ActAldp566 0.000E+00 0.000E+00 1.903E-23 0.000E+00 3.539E-22 4.725E-22 q3=0.12 (H+CH3CO)
4.533E-22 4.458E-22 2.270E-20 2.985E-20 3.199E-20 2.987E-20 q1=0.00 (CH4+CO)
1.923E-20 9.497E-21 3.450E-21 1.914E-22 3.762E-26 0.000E+00 q's based on 1 bar
ActAldp999 0.000E+00 0.000E+00 1.822E-23 0.000E+00 3.389E-22 4.525E-22 wave > 300 nm
4.340E-22 4.269E-22 2.112E-20 2.647E-20 2.740E-20 2.479E-20
1.485E-20 6.739E-21 2.319E-21 1.258E-22 2.790E-26 0.000E+00
MeVK p177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.800E-22 4.760E-21 5.468E-21 5.834E-21
5.243E-21 4.484E-21 3.669E-21 1.710E-21 9.063E-23 0.000E+00
MeVK p566 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.011E-22 2.673E-21 3.070E-21 3.275E-21
2.943E-21 2.517E-21 2.061E-21 9.600E-22 5.079E-23 0.000E+00
MeVK p999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 6.933E-23 1.833E-21 2.106E-21 2.247E-21
2.019E-21 1.725E-21 1.414E-21 6.587E-22 3.477E-23 0.000E+00
MeAcr 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 9.450E-24 2.852E-23 5.252E-23 7.912E-23
1.182E-22 1.500E-22 1.779E-22 1.959E-22 3.982E-23 0.000E+00
GlyAld 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 7.413E-20 1.879E-19 J10
1.038E-19 4.946E-20 5.168E-20 5.719E-20 5.581E-20 4.810E-20
2.912E-20 1.567E-20 7.019E-21 7.099E-22 0.000E+00 0.000E+00
MEKetop177 0.000E+00 0.000E+00 4.387E-22 0.000E+00 4.393E-21 1.291E-21 X67
1.231E-21 1.356E-21 3.133E-20 3.510E-20 3.397E-20 3.077E-20
1.981E-20 1.158E-20 5.697E-21 6.008E-22 2.756E-25 0.000E+00
MEKetop999 0.000E+00 0.000E+00 1.982E-22 0.000E+00 1.984E-21 5.829E-22 X67
5.559E-22 6.123E-22 1.415E-20 1.586E-20 1.534E-20 1.390E-20
8.947E-21 5.232E-21 2.574E-21 2.714E-22 1.244E-25 0.000E+00
PrAld 298 0.000E+00 0.000E+00 1.797E-23 0.000E+00 3.430E-22 5.337E-22 J10
6.041E-22 6.842E-22 2.988E-20 4.520E-20 5.122E-20 5.545E-20
4.628E-20 3.576E-20 2.436E-20 5.836E-21 1.246E-23 0.000E+00
MGlyxlp177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.085E-20 3.955E-20 4.398E-20 4.414E-20
3.504E-20 2.355E-20 1.811E-20 6.006E-21 1.256E-20 7.311E-22
MGlyxlp566 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.085E-20 3.955E-20 4.398E-20 4.414E-20
3.504E-20 2.355E-20 1.811E-20 6.006E-21 7.045E-21 3.425E-22
MGlyxlp999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.085E-20 3.955E-20 4.398E-20 4.414E-20
3.504E-20 2.355E-20 1.811E-20 6.006E-21 5.232E-21 2.154E-22
Glyxlap177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.173E-21 4.354E-21 5.353E-21 6.331E-21
7.090E-21 7.781E-21 7.452E-21 4.214E-21 5.124E-21 4.897E-23
Glyxlap999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 1.173E-21 4.354E-21 5.353E-21 6.331E-21
7.090E-21 7.781E-21 7.452E-21 4.214E-21 2.864E-21 1.927E-23
Glyxlbp177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.378E-21 1.177E-20 1.388E-20 1.453E-20
1.224E-20 9.558E-21 6.758E-21 2.443E-21 7.973E-23 0.000E+00
Glyxlbp999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 3.378E-21 1.177E-20 1.388E-20 1.453E-20
1.224E-20 9.558E-21 6.758E-21 2.443E-21 7.973E-23 0.000E+00
Glyxlcp177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.968E-21 1.178E-20 1.500E-20 1.704E-20
1.636E-20 1.462E-20 1.148E-20 4.054E-21 4.054E-22 2.265E-24
Glyxlcp999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10
0.000E+00 0.000E+00 2.968E-21 1.178E-20 1.500E-20 1.704E-20
1.636E-20 1.462E-20 1.148E-20 4.054E-21 2.775E-22 8.918E-25
Acet-ap177 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 2.312E-20 2.824E-20 1.980E-20
5.927E-21 6.000E-22 5.868E-23 5.934E-25 0.000E+00 0.000E+00
Acet-ap566 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 1.486E-20 1.723E-20 1.240E-20
4.464E-21 7.146E-22 1.171E-22 2.202E-24 0.000E+00 0.000E+00
Acet-ap999 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 1.053E-20 1.237E-20 9.213E-21
3.702E-21 7.100E-22 1.357E-22 3.115E-24 0.000E+00 0.000E+00
Acet-b 235 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 3.678E-22 2.462E-22 1.158E-22
2.648E-23 6.014E-24 1.502E-24 4.211E-26 0.000E+00 0.000E+00
Acet-b 260 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 1.249E-21 1.020E-21 5.664E-22
1.681E-22 4.919E-23 1.477E-23 5.602E-25 0.000E+00 0.000E+00
Acet-b 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 J10c
0.000E+00 0.000E+00 0.000E+00 4.209E-21 4.230E-21 2.804E-21
1.092E-21 4.079E-22 1.496E-22 7.707E-24 0.000E+00 0.000E+00
ONIT1 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 1.099E-20
4.532E-21 1.951E-21 7.550E-22 3.300E-22 0.000E+00 0.000E+00
MPN 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2.601E-20
1.103E-20 5.239E-21 2.793E-21 2.250E-22 0.000E+00 0.000E+00
HPALD 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2.107E-20
3.151E-20 3.995E-20 4.742E-20 5.222E-20 1.064E-20 0.000E+00
EthNit 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 6.902E-20
6.428E-20 5.734E-20 4.883E-20 2.272E-20 0.000E+00 0.000E+00
ProNit 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 5.832E-20
4.196E-20 2.862E-20 1.808E-20 4.216E-21 0.000E+00 0.000E+00
MVKNit 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 9.601E-20
6.372E-20 4.202E-20 2.535E-20 4.860E-21 0.000E+00 0.000E+00
MCRNit 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 1.328E-19
1.262E-19 1.113E-19 1.010E-19 6.449E-20 0.000E+00 0.000E+00
endofJ
---------must have the two blank lines above to closeout the readin-------------
SDE 07/22/13: Added hydroxyacetone from JPL10
SDE 04/16/13: Added H2SO4, Br2, BrNO2 and ClNO2
rev 3/2013c
Major fix to Acetone Xsects - problems with Q-yields
NEW J-Acet-a (CH3O) is 3x (0km) to 5x (5km) faster than ver 6.8
NEW J-Acet-b (CO) is 0.60x slower
Note in lower trop: J-b / J-a = 0.28 (0km) to 0.18 (4km)
Major fixes to incorrect short-w extrap,
inexplicable X-acetone in places incorrect Q's
other temperature fixes. Follows JPL-2010, incl. O3 limited tables.
Differences with 3/2012 FJX_spec.data should be small.
This data set is derived strictly from pratmo 77-bin (has some roundoff differences)
J O2 <1% everywhere
J O3-O1D 3-4% lower everywhere (error in pratmo - FJX bins and QO1d impl.)
J N2O5 -1% at 24km rising to -5% at >28 km (new T's for Xsects)
J HNO3 -1% at 30km up to -5% at 50km
J CH2Br2 +0% to +20% in trop, new, better T's, previous mistake in registation.
J Acetone - still a problem.
The new >200nm code looks fine, loss of J's for w<200nm affects a number of strat
species, incl. CFCs, N2O, etc, plus HNO3.
JPL 2010 rev 3/2012 VOC updates and change in Stern-Volmer method
T is used to get p (or M) from the mean trop lapse rate
thus VOCs are restricted to trop for accurate J's.
requires version fastJX-67
Notes on new J-VOCs in troposphere:
ActAld J is the same
MeVK** J is 1.4x (surface) to 1.0x (tropopause)
MeAcr J is uniformly 0.375x old J: q-yld form 0.008 to 0.003 all w.
GlyAld J is uniformly 1.6x old J
MEKeto J is 1.20 - 1.25x old J
PrAld J is same (as EAld)
MGlyxl** J is about 1.5x old J
Glyxl** total J is about 2 x old J, very different q-yld partitioning
specified at 1 atm only, S-V for w>385 nm
Acet** total J is 0.70x (surf) to 0.20x (200 hPa) old J
change is complex, not obvious with JPL-2010
new Xsect x Qyld is done per formula at each (T,p)
** includes Stern-Volmer dependence merged to (T,p), see C3H6O below.
==============================JX-67 UPDATED VOCs================================
C3H6O = Acet = Acetone = CH3C(O)CH3
Acet-a => CH3CO+CH3
Acet-b => CH3+CH3+CO
q-ylds scale with T & M following trop lapse rate
J10: D20, tbls 4D-23, 4D-24
For Acet-a, there are three tables keyed to three tropospheric pressure levels.
The q(a) is from Stern-Volmer relation
alt= 0 km 5 km 13 km
M= 2.46E+19 1.50E+19 5.8E+18
T= 295K 272K 220K
P = 999 hPa 566 hPa 177 hPa
Pick the pair of tables that best respresent the range of altitudes where Acetone exists
always use the 295K table, pick either 220K (13 km) OR 272K (5 km)
Note that the Acet-b dissociation X-sections are evaluated at 235K but labeled 260K,
as both 235K and 260K are effectively zero J, and using 260K to interpolate
to 295K produces better values for temperature like 278K
GlyAld = Glycol aldehyde = HOCH2CHO
HOCH2CHO + hv
CH2OH + HCO (1) 0.83
CH3OH + CO (2) 0.10
OH + CH2CHO (3) 0.07
J10: D19, tbl 4D-22
Notes: single J-value with fixed q-yields at 298K
Xsect x Qyld at 298K, no better info.
ActAld = Acetaldehyde = CH3CHO
ActAld (a) = CH3+HCO <<<std yield
new ActAlx (b) = CH4+CO <<<only short wavelength
Notes: Qb = 0 in trop, only in strat would it matter, and then only
possibly because it produces CH4. Can be dropped from most models (J=1e-14).
Only T = 298K, JPL-2010 tables 4D-5, 4D-6
Glyxl = Glyoxal (CHO)2
CHOCHO + hv
HCO + HCO (Q1) = Glyxla
H2 + 2 CO (Q2) = Glyxlb
HCHO + CO (Q3) = Glyxlc
J10: D22, tbl 4D-26
Stern-Volmer expression: Qtotal = 1/[6.80 + 251.8e-4 P(Torr)]
Increases quantum yields at low P, but ONLY specified for 390-470 nm
Assume that 220K has P = 0.18 atm and higher q.
MeAcr = Methacrolein CH2C(CH3)CHO
CH2C(CH3)CHO + hv => CH2=C(CH3)+HCO (recommended)
C3H6 + CO
H + CH2=C(CH3)CO
J10: D17, tbl 4D-20
Uncertain q, uses q=0.003 everywhere, single X sects at 298K
MeVK = Methylvinyl ketone = CH3C(O)CH=CH2
=> C3H6+CO [0.6] keep recommended branching ratios from IUPAC
=> CH2CHCO+CH3 [0.4]
J10: D18, tbl 4D-21
Total Q-yld from Stern-Volmer converted (as in acetone) to 3 different trop levels:
alt= 0 km 5 km 13 km
M= 2.46E+19 1.50E+19 5.8E+18
T= 295K 272K 220K
Only apply a single overall quantum yield = exp[-0.055*(w-308)]/5.5+9.2e-19*[M])
Thus there are 3 tables for MeVK, each designated by T(K)
Pick the pair of tables that best respresent the range of altitudes where MeVK exists
always use the 295K table, pick either 220K (13 km) OR 272K (5 km)
MGlyxl = Methyl glyoxal = CH3COC(O)H
CH3COCHO + hv => CH3CO + HCO
J10: D23, tbl 4D-28
Q-yld from Stern-Volmer converted (as in acetone) to 3 different trop levels:
alt= 0 km 5 km 13 km
M= 2.46E+19 1.50E+19 5.8E+18
T= 295K 272K 220K
torr= 760 430 135
Thus there are 3 tables for MGlyxl, each designated by T(K)
Pick the pair of tables that best respresent the range of altitudes where MeVK exists
always use the 295K table, pick either 220K (13 km) OR 272K (5 km)
PrAld = C2H5CHO propionaldehyde (or propanal)
[originally incorrectly called Ethyl aldehyde in previous fastJX]
C2H5CHO => C2H5 + HCO
J10: D3, tbl 4D-7, single table at 298K
MEKeto = Methylethyl ketone = CH3COC2H5
****not listed in JPL-2010***
maintain IUPAC-based X-sections, but adjust/include Stern-Volmer
in the temperature/density profiles consistent with fast-Jx 6.7.
(X-sections scaled by 1/(1 + 2.0*M(bar))
CH3C(O)C2H5 => C2H5+CH3CO [.85] (fixed q-yield)
=> CH3+C2H5CO [.15]
==============================JX-66 UPDATED to JPL-2010=========================
JPL 2010 rev 8/2011 changes compared with previous data set
>>>>>N.B. floowing analysis is for 77-bin pratmo - the fast-JX are different
>>>>>in places because of the combined bins. Beware of changes when J's are very small
>>>>>the lower-case 'x's at the end of the 2nd Xsect title means these are strat only
>>>>> and if W_ <18, they are dropped (can include fro trop Br chemistry by dropping 'x's)
Changes in X's compared with previous data set
NO scaled by 0.6* to reflect known self-abs, better fit (Hsu&Prather, Linoz v3)
O2 revised Herzberg Cont (very small, no change in S-R bands
O3 revised O3, small changes, +0 to +5% at most wavelengths
O3(1D) no changes except for short wavelengths where it drops to 0.48 (ignored before)
N2O 300K & 200K Xsects within +-3% r better, T-dep smooth except w>230nm,
CFCL3 300K identical, 220K has -5%to+15% shift in key region 210-220 nm ??fit
CF2CL2 300k identical, 220K param is 15to25% higher in key region ??fit
F113 300K increase 2%to15% in key region, 20%-40% higher at 220K, funny reverse T-fit
F114 300K increase 10%to30% in key region, 10%-40% higher at 220K, funny reverse T-fit
F115 300K only, identical to 1%
NO2 same as before, but choice to be made on low-T extrapolation of Qyld and Xsects
Qyld recommended only for 248K & 298K, Xsect for 220K & 294K
values at 240K do linear interp, no extrap (hence are too high at 200K)
values at 200K do a log-linear extrap of both Q & X down to 200K (better?)
Notes on the transition from pre-JPL2010 to JPL2010
for all UCI cross sections in reference J-code and in fast-JX (v6.6)
(M. Prather, 2 Aug 2010)
O2
S-R bands have no spcific recommendation, continue to use UCI formulation
Herzberg continuum, unchanged except except JPL-10 truncates the short
wavelengths (fixed).
O3
compared to our original reference X's, both IUPAC aand JPL-10 are 3-5%
larger in the key 200-230 nm region.
reduces J's in 18-40km region by O2(-2% at 40km,-10% at 20km),
N2O-CFCl3-CF2Cl2-CCL4-..(-6%)
CH3Br-halons (-10%),OCS(-15%)
other changes due just to change in fluxes are smaller (+-3%)
J-O3 (3P or 1D) changes only +-2% at most
This following list applies only to changes in the species X's or Q's
J-NO no recommendation, have scaled by 0.60 based on PhotoComp2008 (self-abs)
J-O2 X's unchanged (for impact of O3 new X's see above)
J-O3 small changes (+-3%), discussed above
J-O3(1D) very small changes (+-1%)
J-H2COa increased +10% to +20%
J-H2COb increased +6% to +15%
J-H2O2 increased +5% to +7%
J-CH3OOH increased +5% to +7%
J-NO2 small changes (+-3%)
J-NO3 increased 3%(0km) to 30%(14-40km), Q's similar (Qb=0.120 to 0.112)
J-N2O5 no change at 0km, increased 20(+-5)% in strat (new low-T X's)
J-HNO2 decreased uniformly -20%, need to re-check X's
J-HNO3 very small changes (+-1%)
J-HNO4 increase +13% (0km) to +20% (UT/LS)
J-ClNO3a small changes (+-3%)
J-ClNO3b small changes (+-3%)
J-Cl2 very small changes (+-1%)
J-HOCl very small changes (+-1%)
J-OClO decreased -4% uniform
J-Cl2O2 increased +25% to +30%
J-ClO increased +20%(40km) to +90%(UT/LS)
J-BrO small changes +2% to +5%
J-BrNO3 decreased -5% to -10% in UT/LS
J-HOBr very small changes (+-1%)
J-BrCl small increase +2%
J-N2O small increase +3%
J-CFCl3 decreased -5%
J-CF2Cl2 -3% to +5% in strat where lost
J-F113 increased +5% to +15%
J-F114 very small changes (+-1%)
J-F115 very small changes (+-1%)
J-CCl4 very small changes (+-1%)
J-CH3Cl very small changes (+-1%)
J-MeCCL3 small changes (+-4%)
J-CH2Cl2 no change at 0km, but decreased -15% in UT/LS
J-CHF2Cl increased +3% to +5%
J-F123 very small changes (+-1%)
J-F141b decrease -5% to 0%, centered on UT/LS
J-F142b decrease -3% to 0%
J-CH3Br very small changes (+-1%) where important
J-H1211 small increases from 0% to +5%
J-H1301 small increases from +1% to +4%
J-H2402 decreases -10% to -20%
J-CH2Br2 large increases +150% in trop to 0% in strat
J-CHBr3 increased +2% to +12% from 0-24km
J-CH3I no change in trop, increased +25% in UT/LS
J-CF3I no change in trop, increased +25% in UT/LS
J-OCS very small changes (+-1%) in strat where important
J-PAN very small changes (+-1%)
J-CH3NO3 small decrease in trop (-5%),larger in LS (-25%), major change in X's
J-ActAld >>>none of the VOCs below have been updated as of 3Agu2010
J-MeVK
J-MeAcr
J-GlyAld
J-MEKeto
J-EAld
J-MGlyxl
J-Glyxla
J-Glyxlb
J-Acet-a
J-Acet-b
----------------------------------------------------------------------
Notes (pre JPL-2010):
H2COa => H+HCO
H2COb => H2+CO
NO3 => NO+O2 [0.11414] fixed revised to 0.114
=> NO2+O [0.88586]
HNO2 = HONO
HNO3 = HONO2
HNO4 = HO2NO2
ClNO3 = ClONO2
ClNO3a => Cl+NO3
ClNO3b => ClO+NO2
BrNO3 = BrONO2
MeCCl3 = CH3CCl3
H1211 = CF2ClBr
H1301 = CF3Br
H2402 = C2F4Br2
PAN = Peroxyacetyl nitrate = CH3C(O)COONO2
=>CH3C(O)O2 + NO2
CH3NO3 = CH3ONO2 = Methyl nitrate
=> CH3O + NO2
>>>see notes above for VOCs and new fast-JX 6.7<<<
ActAld = Acetaldehyde = CH3CHO
=> CH3 + HCO
MeVK =Methylvinyl ketone = CH3C(O)CH=CH2
=> C3H6+CO [0.6]
=> CH2CHCO+CH3 [0.4]
to be scaled by density 1/(1 + 1.67e-19*M)
MeAcr = Methacrolein CH2C(CH3)CHO
=> CH2=C(CH3)+HCO
X-sect includes q-yld =0.008
GlyAld = Glycol aldehyde = HOCH2CHO
=> HOCH2 + HCO
X-sect includes q-yld =0.75
MEKeto = Methylethyl ketone = CH3COC2H5
=> C2H5+CH3CO [.85]
=> CH3+C2H5CO [.15]
to be scaled by pressure 1/(1 + 2.0*M(bar))
EAld = Ethyl aldehyde = C2H5CHO
=> C2H5 + HCO
MGlyxl = Methyl glyoxal = CH3COCHO
=> CH3CO + HCO
includes *qyld-0(wvl)
to be scaled by pressure 1/(1 + 4.15*M(bar))
Glyxl = Glyoxal (CHO)2
Glyxla => HCO + HCO wvl < 340 nm
X-sect includes qyld-1 [0.40]
Glyxlb => H2+CO+CO or CO+CH2O wvl > 340 nm
X-sect includes qyld-2 [0.029]
C3H6O = Acet = Acetone = CH3C(O)CH3
Acet-a => CH3CO+CH3
Acet-b => CH3+CH3+CO
q-ylds scale with T and density
---------------------------------------------------------------------------
w-eff (nm) 187. 191. 193. 196. 202. 208.
211. 214. 261. 267. 277. 295.
303. 310. 316. 333. 380. 574.
SUSIM
11Nov1994 low solar
SOL#/cm2/s 1.360E+12 1.591E+12 1.629E+12 9.085E+11 7.674E+12 4.588E+12
9.826E+12 1.209E+13 6.357E+14 4.040E+14 3.152E+14 5.897E+14
7.705E+14 5.054E+14 8.934E+14 3.857E+15 1.544E+16 2.131E+17
std fast-JX = average of the two
SOL#/cm2/s 1.391E+12 1.627E+12 1.664E+12 9.278E+11 7.842E+12 4.680E+12
9.918E+12 1.219E+13 6.364E+14 4.049E+14 3.150E+14 5.889E+14
7.678E+14 5.045E+14 8.902E+14 3.853E+15 1.547E+16 2.131E+17
29Mar1992 med-high solar
SOL#/cm2/s 1.423E+12 1.662E+12 1.699E+12 9.468E+11 8.007E+12 4.771E+12
1.001E+13 1.229E+13 6.370E+14 4.055E+14 3.148E+14 5.880E+14
7.652E+14 5.034E+14 8.869E+14 3.849E+15 1.550E+16 2.131E+17
Corrected NO3 Xsections
New J-NO3 from JPL-2010
NO3a => NO2+O (405 - 640 nm) J_TOA = 0.2075 (190K) 0.1648 (298K)
NO3b => NO+O2 (586 - 640 nm) J_TOA = 0.0295 (190K) 0.0209 (298K)
ratio = b/(a+b) = 0.1245 (190K) 0.1124 (298K)
recommend for fast-JX and pratmo to use a single NO3t Xsection at 190K and 298K
with mean branching ratio: NO3b = 0.118, NO3a = 0.882
can split out and use two separate Xsection for NO3a & NO3b as below.
NO3t 190 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 5.296E-21 1.112E-18
NO3t 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 3.796E-21 8.713E-19
NO3a 190 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 5.296E-21 9.736E-19
NO3a 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 3.796E-21 7.733E-19
NO3b 190 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 1.385E-19
NO3b 298 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 9.797E-20