4-carbon chemistry

src/main/java/gregicality/science/api/unification/materials/GCYSMaterials.java

@@ -210,7 +210,7 @@ public class GCYSMaterials {
     public static Material Tetrabromoethane;
     public static Material TerephthalicAcid;
     public static Material TerephthaloylChloride;
-    public static Material Butanediol;
+    public static Material Butane12diol;
     public static Material GammaButyrolactone;
     public static Material NMethylPyrrolidone;
     public static Material Kevlar;
@@ -244,6 +244,12 @@ public class GCYSMaterials {
     public static Material PedotPSS;
     public static Material PedotTMA;
 
+    public static Material Butane14diol;
+    public static Material Butane23diol;
+    public static Material But1ene;
+    public static Material But2ene;
+    public static Material Isobutene;
+
 
     // Unknown Composition Materials
     public static Material RareEarthHydroxidesSolution;
@@ -295,6 +301,8 @@ public class GCYSMaterials {
     public static Material MediumHyperFuel;
     public static Material HeavyHyperFuel;
 
+    public static Material ButeneOxidesMixture;
+
 
     /**
      * 3100 - 19999

src/main/java/gregicality/science/api/unification/materials/GCYSOrganicChemistryMaterials.java

@@ -318,7 +318,7 @@ public static void init() {
                 .build()
                 .setFormula("C6H4(COCl)2", true);
 
-        Butanediol = new Material.Builder(15047, "butanediol")
+        Butane12diol = new Material.Builder(15047, "butane_12_diol")
                 .fluid()
                 .color(0xAAC4DA)
                 .flags(DISABLE_DECOMPOSITION)
@@ -543,5 +543,39 @@ public static void init() {
                 .components(Edot, 1, PMMA, 2)
                 .cableProperties(V[UEV], 8, 6)
                 .build();
+
+        // FREE ID 15079 - 15090
+
+        Butane14diol = new Material.Builder(15091, "butane_14_diol")
+                .fluid()
+                .color(0xAAC4DA)
+                .components(Carbon, 4, Hydrogen, 10, Oxygen, 2)
+                .build()
+                .setFormula("C4H8(OH)2", true);
+
+        Butane23diol = new Material.Builder(15092, "butane_23_diol")
+                .fluid()
+                .color(0xAAC4DA)
+                .components(Carbon, 4, Hydrogen, 10, Oxygen, 2)
+                .build()
+                .setFormula("C4H8(OH)2", true);
+
+        But1ene = new Material.Builder(15093, "but_1_ene")
+                .fluid(FluidTypes.GAS)
+                .color(0xCF5005)
+                .components(Carbon, 4, Hydrogen, 8)
+                .build();
+
+        But2ene = new Material.Builder(15094, "but_2_ene")
+                .fluid(FluidTypes.GAS)
+                .color(0xCF5005)
+                .components(Carbon, 4, Hydrogen, 8)
+                .build();
+
+        Isobutene = new Material.Builder(15095, "isobutene")
+                .fluid(FluidTypes.GAS)
+                .color(0xCF5005)
+                .components(Carbon, 4, Hydrogen, 8)
+                .build();
     }
 }

src/main/java/gregicality/science/api/unification/materials/GCYSUnknownCompositionMaterials.java

@@ -128,5 +128,9 @@ public static void init() {
         MediumHyperFuel = new Material.Builder(18055, "medium_hyper_fuel").fluid().color(0xDC0A0A).build();
 
         HeavyHyperFuel = new Material.Builder(18056, "heavy_hyper_fuel").fluid().color(0x1E5064).build();
+
+        // FREE ID 18057 - 18067
+
+        ButeneOxidesMixture = new Material.Builder(18068, "butene_oxides_mixture").fluid().color(0xC1DEF7).build();
     }
 }

src/main/java/gregicality/science/common/GCYSConfigHolder.java

@@ -36,6 +36,9 @@ public static class ChainOverrides {
 
         @Config.Comment({"Disables electrolysis of Molybdenite, Powellite, and Wulfenite, requiring Gregicality's processes for Molybdenum.", "Default: true"})
         public boolean disableMolybdenumProcessing = true;
+
+        @Config.Comment({"Disables production of Ethyl Tert-Butyl Ether, requiring Gregicality's process.", "Default: true"})
+        public boolean disableETBEProcessing = true;
     }
 
     public static class CircuitOverrides {

src/main/java/gregicality/science/loaders/recipe/GCYSRecipeLoader.java

@@ -51,6 +51,7 @@ private static void initChains() {
         FantasyMaterials.init();
         SimpleMaterials.init();
         PedotChain.init();
+        C4Chains.init();
     }
 
     private static void initOreProcessing() {

src/main/java/gregicality/science/loaders/recipe/chain/C4Chains.java

@@ -0,0 +1,128 @@
+package gregicality.science.loaders.recipe.chain;
+
+import gregicality.science.common.GCYSConfigHolder;
+import gregtech.api.recipes.GTRecipeHandler;
+import gregtech.api.recipes.ingredients.IntCircuitIngredient;
+import gregtech.api.unification.ore.OrePrefix;
+
+import static gregicality.science.api.recipes.GCYSRecipeMaps.*;
+import static gregicality.science.api.unification.materials.GCYSMaterials.*;
+import static gregtech.api.GTValues.*;
+import static gregtech.api.recipes.RecipeMaps.*;
+import static gregtech.api.unification.material.Materials.*;
+import static gregtech.api.unification.ore.OrePrefix.*;
+
+public class C4Chains {
+    public static void init() {
+        butenes();
+        butane_12_23_diol();
+        butane_14_diol();
+        butadiene();
+        new_etbe();
+    }
+
+    private static void butenes() {
+        // Arbitrary output ratios
+        DISTILLATION_RECIPES.recipeBuilder()
+                .fluidInputs(Butene.getFluid(1000))
+                .fluidOutputs(But1ene.getFluid(250))
+                .fluidOutputs(But2ene.getFluid(500))
+                .fluidOutputs(Isobutene.getFluid(250))
+                .duration(160).EUt(2400)
+                .buildAndRegister();
+    }
+
+    private static void butane_14_diol() {
+        // C2H2 + H2CO -> HO-CH2-C#C-CH2-OH; HO-CH2-C#C-CH2-OH + 4H -> HO-C4H8-OH
+        BURNER_REACTOR_RECIPES.recipeBuilder()
+                .fluidInputs(Acetylene.getFluid(1000))
+                .fluidInputs(Formaldehyde.getFluid(2000))
+                .fluidInputs(Hydrogen.getFluid(4000))
+                .notConsumable(plate, Nickel) //TODO Raney nickel
+                .fluidOutputs(Butane14diol.getFluid(1000))
+                .pressure(3E8).temperature(360)
+                .duration(400).EUt(VA[HV]).buildAndRegister();
+    }
+
+    private static void butane_12_23_diol() {
+        // C4H8 + H2O + O (OsO4 cat.) -> C4H10O2
+        CHEMICAL_RECIPES.recipeBuilder()
+                .fluidInputs(But1ene.getFluid(1000))
+                .fluidInputs(Water.getFluid(1000))
+                .fluidInputs(Oxygen.getFluid(1000))
+                .notConsumable(dust, OsmiumTetroxide) // TODO Upjohn/Sharpless dihydroxylation
+                .fluidOutputs(Butane12diol.getFluid(1000))
+                .duration(300).EUt(VA[EV]).buildAndRegister();
+
+        // C4H8 + H2O + O (OsO4 cat.) -> C4H10O2
+        CHEMICAL_RECIPES.recipeBuilder()
+                .fluidInputs(But2ene.getFluid(1000))
+                .fluidInputs(Water.getFluid(1000))
+                .fluidInputs(Oxygen.getFluid(1000))
+                .notConsumable(dust, OsmiumTetroxide) // TODO Upjohn/Sharpless dihydroxylation
+                .fluidOutputs(Butane23diol.getFluid(1000))
+                .duration(300).EUt(VA[EV]).buildAndRegister();
+
+        // C4H8 + Cl/H2O + NaOH -> C4H8O + NaCl (55% trans-2,3-butene oxide, 30% cis-2,3-butene oxide, and 15% 1,2-butene oxide)
+        CHEMICAL_RECIPES.recipeBuilder()
+                .fluidInputs(Butene.getFluid(1000))
+                .fluidInputs(Chlorine.getFluid(1000))
+                .fluidInputs(Water.getFluid(1000)) // TODO sequential reactor?
+                .input(dust, SodiumHydroxide)
+                .fluidOutputs(ButeneOxidesMixture.getFluid(1000))
+                .output(dust, Salt, 2)
+                .duration(400).EUt(VA[EV]).buildAndRegister();
+
+        // C4H8 + HOCl -> C4H8O + HCl (55% trans-2,3-butene oxide, 30% cis-2,3-butene oxide, and 15% 1,2-butene oxide)
+        CHEMICAL_RECIPES.recipeBuilder()
+                .fluidInputs(Butene.getFluid(1000))
+                .fluidInputs(HypochlorousAcid.getFluid(1000))
+                .fluidOutputs(ButeneOxidesMixture.getFluid(1000))
+                .fluidOutputs(HydrochloricAcid.getFluid(1000))
+                .duration(400).EUt(VA[EV]).buildAndRegister();
+
+        // C4H8O + H2O -> C4H10O2 (Large excess of H2O)
+        BURNER_REACTOR_RECIPES.recipeBuilder()
+                .fluidInputs(ButeneOxidesMixture.getFluid(1000))
+                .fluidInputs(Water.getFluid(8000))
+                .fluidOutputs(Butane23diol.getFluid(850))
+                .fluidOutputs(Butane12diol.getFluid(150))
+                .pressure(5_000_000).temperature(450)
+                .duration(300).EUt(VA[EV]).buildAndRegister();
+    }
+
+    private static void butadiene() {
+        // C4H10O2 (Al2O3 cat.) -> C4H6 + 2 H2O
+        BURNER_REACTOR_RECIPES.recipeBuilder()
+                .fluidInputs(Butane14diol.getFluid(1000))
+                .notConsumable(dust, Alumina)
+                .fluidOutputs(Butadiene.getFluid(1000))
+                .fluidOutputs(Steam.getFluid(2000)) // TODO Superheated Steam
+                .temperature(625)
+                .duration(150).EUt(VA[HV]).buildAndRegister();
+
+        // C4H10O2 (Al2O3 cat.) -> C4H6 + 2 H2O
+        BURNER_REACTOR_RECIPES.recipeBuilder()
+                .fluidInputs(Butane23diol.getFluid(1000))
+                .notConsumable(dust, Alumina)
+                .fluidOutputs(Butadiene.getFluid(1000))
+                .fluidOutputs(Steam.getFluid(2000)) // TODO Superheated Steam
+                .temperature(625)
+                .duration(150).EUt(VA[HV]).buildAndRegister();
+    }
+
+    public static void new_etbe() {
+        if (GCYSConfigHolder.chainOverrides.disableETBEProcessing) {
+            GTRecipeHandler.removeRecipesByInputs(CHEMICAL_RECIPES, Ethanol.getFluid(1000), Butene.getFluid(1000));
+            GTRecipeHandler.removeRecipesByInputs(LARGE_CHEMICAL_RECIPES, Ethanol.getFluid(1000), Butene.getFluid(1000)); // TODO remove once CR recipe removal issue gets fixed
+        }
+
+        BURNER_REACTOR_RECIPES.recipeBuilder()
+                .fluidInputs(Ethanol.getFluid(1000))
+                .fluidInputs(Isobutene.getFluid(1000))
+                .fluidInputs(SulfuricAcid.getFluid(50))
+                .fluidOutputs(EthylTertButylEther.getFluid(1000))
+                .pressure(1_000_000).temperature(350)
+                .duration(400).EUt(VA[HV]).buildAndRegister();
+    }
+}

src/main/java/gregicality/science/loaders/recipe/chain/KevlarChain.java

@@ -57,21 +57,10 @@ public static void init() {
                 .EUt(240)
                 .buildAndRegister();
 
-        // C4H8 + HClO + H2O -> C4H10O2 + HCl
-        CHEMICAL_RECIPES.recipeBuilder()
-                .fluidInputs(Butene.getFluid(1000))
-                .fluidInputs(HypochlorousAcid.getFluid(1000))
-                .fluidInputs(Water.getFluid(1000))
-                .fluidOutputs(Butanediol.getFluid(1000))
-                .fluidOutputs(HydrochloricAcid.getFluid(1000))
-                .duration(60)
-                .EUt(VA[HV])
-                .buildAndRegister();
-
         // C4H10O2 -> C4H6O2 + 4H (4H lost)
         BREWING_RECIPES.recipeBuilder()
                 .input(dust, Copper)
-                .fluidInputs(Butanediol.getFluid(1000))
+                .fluidInputs(Butane14diol.getFluid(1000))
                 .fluidOutputs(GammaButyrolactone.getFluid(1000))
                 .duration(120)
                 .EUt(VA[EV])

src/main/java/gregicality/science/loaders/recipe/chain/PedotChain.java

@@ -18,7 +18,7 @@ public static void init() {
     private static void edot() {
         //C4H10O2 -> C4H6O2 + 4H
         ELECTROLYZER_RECIPES.recipeBuilder()
-                .fluidInputs(Butanediol.getFluid(1000))
+                .fluidInputs(Butane23diol.getFluid(1000))
                 .fluidOutputs(Diacetyl.getFluid(1000))
                 .fluidOutputs(Hydrogen.getFluid(4000))
                 .duration(80).EUt(VA[MV]).buildAndRegister();

src/main/java/gregicality/science/loaders/recipe/chain/PhotoresistivesChain.java

@@ -19,7 +19,7 @@ public static void init() {
     private static void grignardReagent() {
         // C4H10O2 -> C4H8O + H2O
         CHEMICAL_RECIPES.recipeBuilder()
-                .fluidInputs(Butanediol.getFluid(1000))
+                .fluidInputs(Butane14diol.getFluid(1000))
                 .fluidInputs(SulfuricAcid.getFluid(1000))
                 .fluidOutputs(Tetrahydrofuran.getFluid(1000))
                 .fluidOutputs(DilutedSulfuricAcid.getFluid(1500))

src/main/resources/assets/gcys/lang/en_us.lang

@@ -222,7 +222,7 @@ material.bistrichloromethylbenzene=1,4-Bis(trichloromethyl)benzene
 material.tetrabromoethane=Tetrabromoethane
 material.terephthalic_acid=Terephthalic Acid
 material.terephthaloyl_chloride=Terephthaloyl Chloride
-material.butanediol=Butanediol
+material.butane_12_diol=1,2-Butanediol
 material.gamma_butyrolactone=Gamma-Butyrolactone
 material.n_methyl_pyrrolidone=N-Methyl-2-Pyrrolidone
 material.kevlar=Kevlar
@@ -257,6 +257,13 @@ material.polystyrene_sulfonate=Polystyrene Sulfonate
 material.pedot_pss=PEDOT:PSS
 material.pedot_tma=PEDOT-TMA
 
+material.but_1_ene=1-Butene
+material.but_2_ene=2-Butene
+material.isobutene=Isobutene
+material.butane_13_diol=1,3-Butanediol
+material.butane_14_diol=1,4-Butanediol
+material.butane_23_diol=2,3-Butanediol
+
 
 # Unknown Composition Materials
 material.rare_earth_hydroxides_solution=Rare Earth Hydroxides Solution
@@ -311,6 +318,8 @@ material.light_hyper_fuel=Light Hyper Fuel
 material.medium_hyper_fuel=Medium Hyper Fuel
 material.heavy_hyper_fuel=Heavy Hyper Fuel
 
+material.butene_oxides_mixture=Butene Oxides Mixture
+
 
 # Tricorder Info
 behavior.tricorder.current_pressure=Current Pressure: %s Pa